Numerical Problems — Chapter 3: Thermal Physics
Important Formulas:
| Formula | Variables |
|---|---|
| Q = mcΔT | Q = heat (J), m = mass (kg), c = specific heat (J kg⁻¹ K⁻¹), ΔT = temp change |
| Q = mL | L = latent heat (J/kg); for ice fusion: L = 3.36 × 10⁵ J/kg |
| K = °C + 273 | Temperature conversion |
| P₁V₁ = P₂V₂ | Boyle's Law (constant temperature) |
| V₁/T₁ = V₂/T₂ | Charles' Law (constant pressure, T in Kelvin) |
| P₁V₁/T₁ = P₂V₂/T₂ | Combined Gas Law |
Useful values:
- Specific heat of water: c = 4200 J kg⁻¹ K⁻¹
- Specific heat of ice: c = 2100 J kg⁻¹ K⁻¹
- Latent heat of fusion of ice: L_f = 3.36 × 10⁵ J/kg
- Latent heat of vaporisation of water: L_v = 22.6 × 10⁵ J/kg
Problem 1. How much heat is required to raise the temperature of 2 kg of water from 25°C to 75°C? (Specific heat of water = 4200 J kg⁻¹ K⁻¹)
- Mass, m = 2 kg
- Initial temperature, T₁ = 25°C
- Final temperature, T₂ = 75°C
- ΔT = 75 − 25 = 50°C
- c = 4200 J kg⁻¹ K⁻¹
Q = mcΔT = 2 × 4200 × 50
Q = 420,000 J = 4.2 × 10⁵ J
Problem 2. A piece of iron of mass 0.5 kg is heated from 30°C to 130°C. Find the heat absorbed. (Specific heat of iron = 470 J kg⁻¹ K⁻¹)
- Mass, m = 0.5 kg
- ΔT = 130 − 30 = 100°C
- c = 470 J kg⁻¹ K⁻¹
Q = mcΔT = 0.5 × 470 × 100
Q = 23,500 J = 2.35 × 10⁴ J
Problem 3. How much heat is required to melt 5 kg of ice at 0°C? (Latent heat of fusion of ice = 3.36 × 10⁵ J/kg)
- Mass, m = 5 kg
- Latent heat of fusion, L_f = 3.36 × 10⁵ J/kg
- The melting happens at constant temperature (0°C)
Q = mL_f = 5 × 3.36 × 10⁵
Q = 16.8 × 10⁵ J = 1.68 × 10⁶ J
Problem 4. How much heat is needed to convert 2 kg of water at 100°C to steam at 100°C? (Latent heat of vaporisation = 22.6 × 10⁵ J/kg)
- Mass, m = 2 kg
- Temperature = constant at 100°C
- L_v = 22.6 × 10⁵ J/kg
Q = mL_v = 2 × 22.6 × 10⁵
Q = 45.2 × 10⁵ J = 4.52 × 10⁶ J
Note: This is more than 5× the heat needed to heat the same mass of water from 0°C to 100°C (Q = 2 × 4200 × 100 = 840,000 J), which is why steam burns are so severe.
Problem 5. A 200 g block of copper (specific heat = 385 J kg⁻¹ K⁻¹) at 80°C is dropped into 500 g of water at 20°C. Find the final temperature of the mixture. (Specific heat of water = 4200 J kg⁻¹ K⁻¹)
- m_copper = 200 g = 0.2 kg; c_copper = 385 J kg⁻¹ K⁻¹; T_copper = 80°C
- m_water = 500 g = 0.5 kg; c_water = 4200 J kg⁻¹ K⁻¹; T_water = 20°C
- Final temperature = T (same for both at equilibrium)
By principle of calorimetry: Heat lost by copper = Heat gained by water
m_c × c_c × (80 − T) = m_w × c_w × (T − 20)
0.2 × 385 × (80 − T) = 0.5 × 4200 × (T − 20)
77(80 − T) = 2100(T − 20)
6160 − 77T = 2100T − 42000
6160 + 42000 = 2100T + 77T
48160 = 2177T
T = 48160 / 2177 ≈ 22.1°C
Problem 6. Convert: (a) 100°C to Kelvin (b) 373 K to Celsius (c) 0 K to Celsius
(a) K = °C + 273 = 100 + 273 = 373 K
(b) °C = K − 273 = 373 − 273 = 100°C
(c) °C = K − 273 = 0 − 273 = −273°C (absolute zero)
Problem 7. A gas has a volume of 4 L at 27°C. If it is heated at constant pressure to 127°C, find the new volume. (Use Charles' Law)
- V₁ = 4 L
- T₁ = 27°C = 27 + 273 = 300 K
- T₂ = 127°C = 127 + 273 = 400 K
- V₂ = ?
By Charles' Law: V₁/T₁ = V₂/T₂
V₂ = V₁ × T₂/T₁ = 4 × 400/300 = 4 × 4/3 = 16/3 ≈ 5.33 L
Problem 8. A gas occupies 500 mL at a pressure of 2 atm. Find the volume when the pressure is reduced to 1 atm at constant temperature. (Use Boyle's Law)
- P₁ = 2 atm; V₁ = 500 mL
- P₂ = 1 atm; V₂ = ?
By Boyle's Law: P₁V₁ = P₂V₂
V₂ = P₁V₁ / P₂ = (2 × 500) / 1 = 1000 mL = 1 L
Summary Table
| Situation | Formula | Key value to remember |
|---|---|---|
| Heating/cooling a substance | Q = mcΔT | c_water = 4200 J kg⁻¹ K⁻¹ |
| Melting ice | Q = mL_f | L_f = 3.36 × 10⁵ J/kg |
| Boiling water | Q = mL_v | L_v = 22.6 × 10⁵ J/kg |
| Calorimetry | Heat lost = Heat gained | — |
| Charles' Law | V₁/T₁ = V₂/T₂ | T must be in Kelvin |
| Boyle's Law | P₁V₁ = P₂V₂ | Temperature constant |
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